Sains Malaysiana 45(8)(2016): 1259–1263
Kajian
Sifat Mekanik Nanokomposit Epoksi Berpenguat Gentian Hibrid Nanotiub
Karbon dan Nanozarah Tanah Liat
(Mechanical
Properties Study of Epoxy Nanocomposite Reinforced Hybrid Fibre
Carbon Nanotubes and Nano Clay)
MOHD HAFIZUDDIN
AB
GHANI1*,
MOHD
NAZRY
SALLEH1,
RUEY
SHAN
CHEN1,
SAHRIM AHMAD1, ISMAIL HANAFI1,
NISHATA
ROYAN
RAJENDRAN
ROYAN2
& MOHD NAZRI
IDRIS3
1Pusat Pengajian
Fizik Gunaan, Fakulti Sains dan Teknologi, Universiti Kebangsaan
Malaysia
43600 Bangi, Selangor Darul Ehsan,
Malaysia
2Jabatan Kejuruteraan
Mekanik dan Bahan, Fakulti Kejuruteraan dan Alam Bina, Universiti
Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia
3Pusat Pengajian
Kejuruteraan Bahan dan Sumber Mineral, Universiti Sains Malaysia,
Kampus Kejuruteraan, 14300 Nibong Tebal, Pulau Pinang, Malaysia
Diserahkan: 20 April 2015/Diterima:
20 November 2015
ABSTRAK
Penyelidikan ini dijalankan
bagi mengkaji sifat mekanik nanokomposit epoksi berpenguat gentian
hibrid nanotiub karbon berbilang dinding (MWCNT) dan nanozarah tanah liat
(NC).
Nanokomposit berpenguat hibrid nanozarah telah disediakan melalui
kaedah kacauan mekanik dan sampel dengan jumlah nanozarah berbeza
dibentuk menggunakan pengacuan mampatan. Dalam ujian lenturan yang
dijalankan, didapati sampel hibrid memberikan nilai kekuatan yang
lebih tinggi berbanding sampel tunggal. Ujian terhadap sifat hentaman
nanokomposit epoksi berpenguat gentian nanozarah menunjukkan bahawa
penambahan gentian terhadap sampel tidak dapat meningkatkan sifat
ketahanan daya hentaman yang dikenakan. Namun demikian, sampel yang
mengandungi gentian hibrid nano merekodkan nilai daya tahan hentaman
yang lebih tinggi berbanding sampel tunggal. Mikrograf pengimbas
elektron (SEM)
mengesahkan kesan serakan pengisi hibrid dan ikatan antara muka
dalam matriks yang baik. Ini membuktikan bahawa gentian hibrid antara
nanotiub karbon dan nanozarah tanah liat pada kandungan komposisi
tertentu dapat menambahbaik sifat mekanik bahan nanokomposit.
Kata kunci: Epoksi; nanokomposit;
nanotiub karbon; nanozarah tanah liat; pengisi hybrid
ABSTRACT
The study was performed to
investigate the mechanical properties of epoxy nanocomposite reinforced
hybrid fibre multi-wall carbon nanotubes (MWCNT) and nanoclay (NC).
Nanocomposite hybrid nanoparticles were prepared by using mechanical
stirrer and compression molding. From the flexural test measurements,
the hybrid specimens gave higher strength than those of the other
samples. The impact testing showed that the addition of nanoparticles
to the sample cannot increase the samples properties. Scanning electron
micrograph (SEM)
shows better dispersion of hybrid filler in the matrix, that proves
hybrid carbon nanotubes and nanoclay on certain amount of ratios
can improve the mechanical properties of nanocomposite materials.
Keywords: Carbon nanotubes; epoxy; hybrid filler; nanoclay; nanocomposite
RUJUKAN
Abdul Rahman Mohamed.
2006. Nanotiub Karbon: Penemuan Sains yang Merevolusikan Nanoteknologi.
Syarahan Umum Profesor. Pulau Pinang: Universiti Sains Malaysia.
Ayatollahi, M.R.,
Shadlou, S. & Shokrieh, M.M. 2011. Fracture toughness of epoxy/multi-walled
carbon nanotube nano-composites under bending and shear loading
conditions. Materials & Design 32(4): 2115-2124.
Che Som Sulaiman,
Sahrim Ahmad & Ibrahim Abdullah. 1994. Kajian adunan getah asli/polietilena
berketumpatan tinggi dengan getah asli cecair sebagai pengserasi.
Sains Malaysiana 23: 29-38.
Chowdary, M.S.
& Kumar, M.N. 2015. Effect of nanoclay on the mechanical properties
of polyester and s-glass fiber (Al). International Journal of
Advanced Science and Technology 74: 35-42.
Gkikas, G., Barkoula,
N.M. & Paipetis, A.S. 2012. Effect of dispersion conditions
on the thermo-mechanical and toughness properties of multi walled
carbon nanotubes-reinforced epoxy. Composites Part B: Engineering
43(6): 2697-2705.
Haq, M., Burgueno,
R., Mohanty, A.K. & Misra, M. 2008. Hybrid bio-based composites
from blends of unsaturated polyester and soybean oil reinforced
with nanoclay and natural fibers. Composites Science and Technology
68: 3344-3351.
Jin, H.S., Park,
Y.B. & Yoon, K.H. 2007. Rheological and mechanical properties
of surface modified multi-walled carbon nanotube-filled PET composite.
Composites Science and Technology 67: 3434-3441.
Ibrahim Abdullah,
Sahrim Ahmad & Che Som Sulaiman. 1994. Termoplastik dari adunan
getah asli (NR) dan polietilena berketumpatan rendah (LLDPE). Laporan
Teknik FSFG 4: 169-183.
Jin, F.L. &
Park, S.J. 2013. Recent advances in carbon-nanotube-based epoxy
composites. Carbon Letters 14(1): 1-13.
Kim, B.C., Park,
S.W. & Lee, D.G. 2008. Fracture toughness of the nano-particle
reinforced epoxy composite. Composite Structures 86: 69-77.
Kaempfer, D., Thomann,
R. & Mülhaupt, R. 2002. Melt compounding of syndiotactic polypropylene
nanocomposites containing organophilic layered silicates and in
situ formed core/shell nanoparticles. Polymer 43: 2909-2916.
Mustaffa Haji Abdullah.
1991. Sains Bahan. Vol. 1. Kuala Lumpur: Dewan Bahasa dan
Pustaka.
Montazeri, A. &
Montazeri, N. 2011. Viscoelastic and mechanical properties of MWNT/epoxy
composites with different nanotube content. Materials and Design
32: 2301-2397.
Noum, S.Y.E., Ahmad,
S., Rasid, R., Hock, Y.C., Seng, L.Y. & Tarawneh, M.A.A. 2014.
Preparation and characterisation of epoxidized natural rubber reinforced
epoxy nanocomposites. Sains Malaysiana 43(8): 1231-1237.
Rhim, J., Hong,
S. & Ha, C. 2009. Tensile, water vapor barrier and antimicrobial
properties of PLA/Nanoclay composites films. LWT-Food Science
and Technology 42: 612-617.
Treacy, M.M.J.,
Ebbesen, T.W. & Gibson, J.M. 1996. Exceptionally high Young’s
modulus observed for individual carbon nonotubes. Nature 381(6584):
678-680.
Wang, W.S., Chen,
H.S., Wu, Y.W., Tsai, T.Y. & Cheng-Yang, Y.W. 2008. Properties
of novel epoxy/clay nanocomposites prepared with a reactive phosphorous-containing
organoclay. Polymer 49: 4826-4836.
*Pengarang untuk surat-menyurat; email:
mhafizuddinabghani@gmail.com
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